Ionization potential of radium monofluoride
S. G. Wilkins🇺🇸 · H. A. Perrett🇬🇧 · S. M. Udrescu🇺🇸 · A. A. Kyuberis🇳🇱 · L. F. Pašteka🇳🇱 · M. Au🇨🇭 · I. Belošević🇨🇦 · R. Berger🇩🇪 · C. L. Binnersley🇬🇧 · M. L. Bissell🇬🇧 · A. Borschevsky🇳🇱 · A. A. Breier🇩🇪 and 34 other authors
The ionization potential (IP) of radium monofluoride (RaF) was measured to be 4.969(2)[10] eV, revealing a relativistic enhancement in the series of alkaline earth monofluorides. The results are in agreement with a relativistic coupled-cluster prediction of 4.969[7] eV, incorporating up to quantum electrodynamics corrections. Using the same computational methodology, an improved calculation for the dissociation energy () of 5.54[5] eV is presented. This confirms that radium monofluoride joins the small group of diatomic molecules for which , paving the way for precision control and interrogation of its Rydberg states.